Monoclinic form of (Z)-1-ferrocenyl-3-(3-hydroxyanilino)but-2-en-1-one
نویسندگان
چکیده
The title compound, [Fe(C(5)H(5))(C(15)H(14)NO(2))], is a monoclinic polymorph of the previously reported triclinic form [Shi et al. (2006 ▶). Acta Cryst. C62, m407-m410]. The polymorphs feature the same strong intra-molecular N-H⋯O=C hydrogen bonds, but show different packing modes. The mol-ecules in the monoclinic form associate into double chains via O-H⋯O=C and (Cp)C-H⋯O-H inter-actions.
منابع مشابه
Zeitschrift für Naturforschung / B / 50 (1995)
According to a single crystal X-ray structure determination all three ferrocenyl substituents of triferrocenylborane (1) adopt the same orientation with respect to the BC3-plane [P 2Jc\ monoclinic; Z = 4; a = 1353.5(3), b = 1695.6(3), c = 1056.4(2) pm, ß = 109.27(3)°]. The simu lated X-ray powder pattern of the single crystal is identical with the powder diagram of a macroscopic sample, indica...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011